<i>d</i><sup>5</sup> off-centering induced ferroelectric and magnetoelectric correlations in trirutile-Fe<sub>2</sub>TeO<sub>6</sub>

نویسندگان

چکیده

We present the rare existence of d5 off-centering, weak ferroelectric polarization and demonstrate its correlation with observed magnetoelectric (ME) properties in G type (TN~210 K) antiferromagnet Fe2TeO6 (FTO) compound. The origin ferroelectricity (FE) is associated both lattice asymmetric electron density distribution around ion cores. ME coupling magnetic field-dependent polarization, voltage, magnetostrain measurements. Short-range ordering due to intrabilayer dimeric exchange via double oxygen bridged Fe-O1-Fe pathway proposed play a dominating role exhibit negative nonlinear field dependent behavior at 300 K. Interbilayer Fe-O2-Fe pathways dominantly determines hysteretic response below TN. signifies magnetoelasticity as manifested temperature strain measurement. Hence by presented FTO.

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ژورنال

عنوان ژورنال: Journal of Applied Physics

سال: 2021

ISSN: ['1089-7550', '0021-8979', '1520-8850']

DOI: https://doi.org/10.1063/5.0063548